11.8
Wave Nature of Matter
Dual Nature of Radiation and Matter · CBSE
Theory
What this section has to deliver
- de Broglie's argument in words, the relation with its accelerated-particle forms, the consistency check with a photon, and the ratio problems. Two- and three-mark questions here are nearly always a ratio of de Broglie wavelengths for proton, deuteron, alpha particle or electron.
Duality, in both directions
- The wave nature of light shows up in interference, diffraction and polarisation. The particle nature shows up in the photoelectric effect and the Compton effect, which involve energy and momentum transfer.
- Which description fits depends on the experiment. Seeing an object needs both: the eye lens gathers and focuses light, which the wave picture describes; the rods and cones absorb it, which needs the photon picture.
- de Broglie's argument (1924), to write out in the exam: nature is symmetrical, and matter and radiation are the two basic physical entities of the universe, so they should be symmetrical in character. If radiation has a dual wave-particle nature, matter should have one too. Moving particles of matter should therefore display wave-like properties under suitable conditions.
The de Broglie relation
- = de Broglie wavelength (m), = momentum (kg m s), = mass (kg), = speed (m s). The waves associated with moving material particles are called matter waves or de Broglie waves.
- The duality is contained in the equation itself: on the left is a wave attribute, on the right a particle attribute, and Planck's constant relates the two.
- The de Broglie wavelength is independent of the charge and of the nature of the particle. It depends only on the momentum.
- It is measurable only for sub-atomic particles, whose masses and momenta are small enough to give wavelengths of the order of atomic spacings in crystals. For everyday objects it is hopelessly small.
Consistency with the photon
- For a photon, . Substituting into the de Broglie relation:
- which is exactly the wavelength of the electromagnetic radiation of which the photon is a quantum. The de Broglie relation, invented for matter, reproduces the right answer for radiation.
Forms for accelerated and energetic particles
- = kinetic energy in joule; = charge in coulomb; = accelerating potential difference in volt, using for a particle starting from rest. Non-relativistic only.
- For an electron this reduces to the number worth memorising:
- At V, Å. At kV, m.
- Dependences to state when asked: , , , . Increasing the accelerating potential decreases ; decreasing the speed increases .
Graphs
- against : from , a rectangular hyperbola — a decreasing curve, concave upwards, approaching but never touching either axis. Never a straight line.
- against kinetic energy: from , so is constant. A steeply falling curve that flattens out as grows, never touching either axis.
- against accelerating potential: same shape, since .
Worked ratio problems
| Comparison | Condition | Result |
|---|---|---|
| Proton and -particle | same accelerating potential | |
| Deuteron and -particle | same accelerating potential | |
| Proton and -particle | same kinetic energy | |
| Proton and -particle | same speed | |
| Proton and deuteron | same speed | |
| Proton and electron | same speed | |
| Proton and -particle | same | and |
| Two fragments of a body at rest | momentum conservation |
- Method for the first row: , so at the same , .
- Method for the second row: a deuteron has and charge , an alpha particle and charge , so .
- Method for the last row: a body at rest splitting in two gives , so the momenta are equal in magnitude, so whatever the masses.
- Accelerated through the same potential, and : of a proton and a deuteron, the proton has the greater wavelength and the smaller momentum. Of an electron and a proton, the electron has the greater wavelength and the smaller momentum.
Other standard results
- Photon and electron of the same wavelength : the electron's kinetic energy is and the photon's energy is , so
- Photoemission by X-rays with the work function negligible: all the photon energy becomes kinetic energy, , so and the emitted electron's de Broglie wavelength is , i.e. . The graph of against is the same steeply falling hyperbola-like curve.
- Electron microscope: at kV the electron wavelength is about m, while yellow light is about to Å, i.e. of order m — some times larger. Resolving power varies inversely with the wavelength used, so the electron microscope's resolving power is about times that of an optical microscope, other factors such as numerical aperture being the same.
Why matter waves are invisible in daily life
- A ball of mass kg at m s: kg m s and m — beyond any measurement.
- A ball of mass kg at m s: kg m s and m, about times the size of a proton.
- An electron at m s: kg m s and nm — comparable to X-ray wavelengths, and to the spacing of atomic planes in a crystal, so it is measurable.
- The lesson: is smaller for a heavier or faster particle, which is why the wave character of matter is significant only in the sub-atomic domain.
A caution NCERT adds
- The wavelength of a matter wave, , has physical significance. The phase velocity of the matter wave has none. The group velocity is physically meaningful and equals the velocity of the particle.
Theory Questions Asked on This Subtopic
Real board questions. Answers are at the end of the page.
- 1
How will the de Broglie wavelength associated with an electron be affected when (i) the velocity of the electron decreases, and (ii) the accelerating potential is increased? Justify your answer.
- 2
An electron is accelerated through a potential difference of 100 V. Calculate the de Broglie wavelength associated with it.
- 3
A proton and a deuteron are moving with the same speed. Find the ratio of the de Broglie wavelength () associated with them.
- 4
A proton and an electron have equal speeds. Find the ratio of de Broglie wavelengths associated with them.
- 5
Draw a plot showing the variation of de-Broglie wavelength of an electron as a function of its K.E.
- 6
What are matter waves? A proton and an alpha particle are accelerated through the same potential difference. Find the ratio of the de Broglie wavelength associated with the proton to that with the alpha particle.
- 7
(a) Calculate the energy and momentum of a photon in a monochromatic beam of wavelength 331.5 nm. (b) How fast should a hydrogen atom travel in order to have the same momentum as that of the photon in part (a)?
- 8
An -particle and a proton are accelerated through the same potential difference. Find the ratio of their de Broglie wavelengths.
- 9
The wavelength of a photon and the de Broglie wavelength of an electron have the same value. Show that the energy of a photon is times the kinetic energy of the electron, where , and have their usual meaning.
- 10
A proton and an -particle have the same de-Broglie wavelength. Determine the ratio of (i) their accelerating potentials, (ii) their speeds.
- 11
A proton and a deuteron are accelerated through the same accelerating potential. Which one of the two has (a) greater value of de-Broglie wavelength associated with it, and (b) less momentum? Give reasons to justify your answer.
- 12
X-rays fall on a photosensitive surface to cause photoelectric emission. Assuming that the work function of the surface can be neglected, find the relation between the de-Broglie wavelength () of the electrons emitted and the energy () of the incident photons. Draw the nature of the graph for as a function of .
- 13
(a) A proton and an -particle are moving with the same speed. Which one of them has the greater value of de Broglie wavelength associated with it? Justify your answer. (b) Lights of wavelengths 430 nm, 450 nm and 660 nm are incident on a metal surface whose threshold wavelength is 600 nm. In which case/cases will photoemission take place, and why? Calculate the threshold frequency of the metal surface.
- 14
Obtain an expression for the ratio of the accelerating potentials required to accelerate a proton and an -particle to have the same de-Broglie wavelength associated with them.
- 15
(a) An electron and a proton are accelerated through the same potential. Which one of the two has (i) greater value of de-Broglie wavelength associated with it, and (ii) lesser momentum? Justify your answer in each case. (b) How is the momentum of a particle related with its de-Broglie wavelength? Show the variation on a graph.
- 16
An electron microscope uses electrons accelerated by a voltage of 50 kV. Determine the de Broglie wavelength associated with the electrons. Taking other factors, such as numerical aperture etc. to be the same, how does the resolving power of an electron microscope compare with that of an optical microscope which uses yellow light?
Numericals
Every numerical set on this subtopic. Full working is at the end of the page.
- 17
A photon and an alpha particle have the same kinetic energy. The ratio of de Broglie wavelengths associated with the proton to that with the alpha particle is
- (a)
1
- (b)
2
- (c)
- (d)
- (a)
- 18
Which of the following graphs correctly represents the variation of a particle's momentum with its associated de-Broglie wavelength?
- (a)
vs : straight line through origin, positive slope
- (b)
vs : concave curve rising steeply near
- (c)
vs : straight line, negative slope
- (d)
vs : rectangular hyperbola (decreasing curve, concave up)
- (a)
- 19
A heavy particle initially at rest splits spontaneously into two particles of masses and having non-zero velocities. The ratio of de Broglie wavelengths associated with the particles is
- (a)
- (b)
- (c)
1
- (d)
- (a)
- 20
The graph showing the correct variation of linear momentum () of a charged particle with its de-Broglie wavelength () is
- (a)
vs : straight line, negative slope through the axes (linear decrease)
- (b)
vs : rectangular-hyperbola-like decreasing curve, concave up
- (c)
vs : increasing concave curve starting from origin
- (d)
vs : straight line through origin, positive slope
- (a)
Answers & Solutions
Work the questions above first, then check yourself here. Each answer is set out the way it should be written in the paper.
De Broglie wavelength: (i) When velocity decreases, INCREASES (since ). (ii) . When the accelerating potential increases, the de Broglie wavelength DECREASES.
; with : ,
, so constant. The graph of vs is a rectangular-hyperbola-like decreasing curve (steeply falling as increases from zero, then flattening out), never touching either axis.
According to Louis de Broglie, a wave is associated with every moving particle; these are called matter waves. de Broglie wavelength of a charged particle accelerated through a potential difference : For proton and -particle charges are and respectively, and :
(a) Energy: Momentum: (b) For a hydrogen atom of mass kg:
; for proton () and -particle (): , i.e. .
de Broglie wavelength of electron: Kinetic energy of electron: Energy of photon of the same wavelength : Dividing (ii) by (i): , as required.
. Here , , , . (i) Since : (ii) ; for the same :
(for the same , assuming charge for both). (a) Since the deuteron's mass is greater than the proton's, the proton (smaller mass) has the GREATER de Broglie wavelength. (b) Momentum . Since the deuteron's mass is greater, the proton (smaller mass) has LESS momentum.
Neglecting the work function, by Einstein's photoelectric equation: de Broglie wavelength of the emitted electron: , i.e. . The graph of vs is a steeply decreasing curve (rectangular-hyperbola-like, constant), never touching either axis.
(a) (for the same ). With : , , so ; the PROTON, having less mass, has the greater de Broglie wavelength. (b) Energies of the incident photons using : for nm, eV; for nm, eV; for nm, eV. Threshold energy for nm: eV. Since and both exceed , photoemission takes place for wavelengths 430 nm and 450 nm; since , photoemission does NOT occur for 660 nm. Threshold frequency:
. Let proton () and -particle () have the same .
(a) de Broglie wavelength for a particle of charge accelerated through potential : , so (for the same ). (i) As the electron's mass is much less than the proton's, the ELECTRON has the greater de Broglie wavelength. (ii) Momentum . As the electron's mass is lesser than the proton's, the momentum of the ELECTRON is lesser than that of the proton. (b) , i.e. — momentum is inversely proportional to de Broglie wavelength. It shows a rectangular hyperbola in the - graph.
For a yellow-light optical microscope, wavelength – Å, i.e. m — roughly times larger than the electron's de Broglie wavelength found above ( m). Resolving power of a microscope is INVERSELY proportional to the wavelength used. Since the electron's de Broglie wavelength is vastly smaller than that of yellow light, the resolving power of an electron microscope is MUCH GREATER than that of an optical microscope using yellow light.
De Broglie wavelength: , and For the same kinetic energy : Since : . Option (b).
: the graph is a rectangular hyperbola. Option (d).
By conservation of momentum, since the particle was initially at rest: . Option (c).
, i.e. momentum is inversely proportional to wavelength — the graph is a rectangular hyperbola (decreasing, concave up). Option (b).