11.4
Experimental Study of Photoelectric Effect
Dual Nature of Radiation and Matter · CBSE
Theory
What this section has to deliver
- This is the highest-yield section in the chapter. A 3-mark answer here needs the apparatus, the relevant graph drawn and labelled, and the observation stated with its reason. A 5-mark answer needs the full list of four observations. Almost every graph question CBSE has set on this chapter lives here.
The apparatus, described in words
- An evacuated glass or quartz tube encloses a thin photosensitive plate C (the emitter, acting as cathode) and another metal plate A (the collector, acting as anode).
- Monochromatic light of sufficiently short wavelength from a source S passes through a window W and falls on C. The window is of transparent quartz sealed into the glass, because quartz — unlike ordinary glass — transmits ultraviolet radiation.
- A battery with a sliding contact maintains a variable potential difference between C and A. A commutator reverses the polarity, so A can be held at any desired positive or negative potential with respect to C.
- A voltmeter across the plates reads the potential difference; a microammeter in series reads the photocurrent.
- Four things can be varied: the intensity of the light, its frequency, the potential difference between the plates, and the material of plate C.
- Frequency is varied by putting a coloured filter or coloured glass in the beam. Intensity is varied by changing the distance of the source from the emitter.
Effect of intensity on photocurrent
- Method: hold A at a fixed positive potential and hold the frequency fixed; vary the intensity and read the current each time.
- Result: the photocurrent increases linearly with intensity. The graph of photocurrent against intensity is a straight line through the origin.
- Reason: the photocurrent is proportional to the number of photoelectrons emitted per second, and that number is proportional to the number of photons striking the surface per second, i.e. to the intensity.
Effect of collector plate potential
- Method: fix the frequency and the intensity ; make A positive and increase its potential gradually.
- The current increases with increasing accelerating potential, then flattens out: at some positive potential every electron emitted by C reaches A, and the current can rise no further. That maximum is the saturation current.
- Now reverse the polarity and make A increasingly negative. The electrons are repelled and only the most energetic reach A, so the current falls rapidly, reaching zero at a sharply defined critical value .
- Definition: the stopping (cut-off) potential is the minimum negative retarding potential applied to the collector plate for which the photoelectric current becomes zero.
- Since the retarding potential just stops even the most energetic photoelectrons,
- Repeat with the same frequency but higher intensities : the saturation currents rise, but all three curves cut the potential axis at the same . For a given frequency the stopping potential is independent of intensity, so is independent of intensity.
- Describing this graph in an exam: three curves of identical shape, all zero at the same negative potential , rising steeply through the origin region and saturating at three different levels, the highest level belonging to the highest intensity. Label the axes "photoelectric current" (vertical) and "collector plate potential" (horizontal, with negative values to the left of O).
Effect of frequency on stopping potential
- Method: keep the intensity the same at various frequencies, and for each record the photocurrent against collector plate potential.
- Result: the same saturation current for all of them (the intensity has not changed, so the number of photoelectrons per second has not changed), but different stopping potentials. Higher frequency gives a more negative stopping potential: for , the stopping potentials satisfy in magnitude.
- Plotting against for a given material gives a straight line, which shows two things: (i) varies linearly with ; (ii) there is a minimum cut-off frequency at which is zero.
- Implications: varies linearly with and is independent of intensity; and below there is no emission at all, however large the intensity.
The four observations to list
- For a given photosensitive material and a frequency above threshold, the photoelectric current is directly proportional to the intensity of the incident light.
- For a given material and frequency, the saturation current is proportional to intensity while the stopping potential is independent of intensity.
- For a given material there is a threshold frequency below which no photoemission occurs, however intense the light. Above , the stopping potential — and equivalently — increases linearly with frequency and is independent of intensity.
- Photoelectric emission is instantaneous, with no apparent time lag: about s or less, even when the incident radiation is exceedingly dim.
Reading the graphs in the exam
| What the question shows | What to say |
|---|---|
| Two photocurrent curves with the same -intercept, different saturation levels | same frequency and same material; different intensities, the higher saturation current being the higher intensity |
| Three curves with the same saturation level, different -intercepts | same intensity; different frequencies, the most negative stopping potential being the highest frequency |
| Curves whose -intercepts differ | different stopping potentials, so different material (or different frequency) |
| Point where the current first becomes non-zero on the negative axis | the stopping potential |
| The horizontal axis of a photocurrent curve | collector (anode) plate potential |
| Two parallel – lines | same slope ; the line meeting the axis at the higher is the metal of greater work function and smaller threshold wavelength |
Do the photoelectrons all have the same energy?
- No. Electrons in a metal do not all occupy the same energy level — some are more tightly bound, and some start from deeper inside and lose energy on the way out. Photoelectrons therefore emerge with a range of kinetic energies, from zero up to .
- CBSE's assertion-reason question on this point: the assertion (that there is a spread of kinetic energies) is true, but the reason usually offered — that electrons lose energy in collisions with atoms — is not the accepted explanation. The accepted reason is that the electrons do not all have the same binding energy to begin with.
Worked numericals of this type
- Photons of energy eV give a stopping potential of V. Then eV.
- Work function eV, incident frequency Hz. J eV; eV; V.
- Light of Å on a metal of work function eV. eV, so eV. Doubling the intensity changes the stopping potential not at all; only the photocurrent rises.
- Stopping potential is V at nm; find it at nm. The work function is unknown, so subtract the two forms of the equation and it cancels: . With eV nm (from eV s), eV and eV, so V and V. Some printed keys quote V here by subtracting instead of ; the difference of the two photon energies is the quantity you need, so write both energies out before subtracting.
- Laser of power W at Hz: photons per second.
- Photon of energy eV: Hz.
- Two frequencies at the same intensity: since , the lower frequency delivers more photons per second, so it emits more electrons; but gives the greater .
- Radiation of Å has eV, so Na ( eV) emits and Mo ( eV) does not. Bringing the laser closer raises only the intensity, so Mo still does not emit and Na merely gives a larger current.
Theory Questions Asked on This Subtopic
Real board questions. Answers are at the end of the page.
- 1
If the frequency of the radiation incident on a photosensitive surface increases (), how will the stopping potential change?
- 2
The three curves shown below represent the variation of photocurrent and applied voltage for two different materials, using two different intensities of a monochromatic light. Identify the two curves which are for the same material. (Graph description: three curves labelled 1, 2, 3 of photocurrent versus applied voltage , each rising from a common negative-voltage cut-off region and saturating at different levels; curves 1 and 2 begin their rise at the SAME (negative) stopping-potential value on the -axis, while curve 3 begins its rise at a different, more negative stopping-potential value.)
- 3
In photoelectric effect, does the photoelectric current depend on the intensity of incident radiation? Give reasons.
- 4
For the light of wavelength 400 nm incident on the cathode of a photocell, the stopping potential is 6 V. If the wavelength of incident light is increased to 600 nm, calculate the new stopping potential. (Take eV s)
- 5
(i) Monochromatic light of frequency Hz is produced by a laser. The power emitted is W. Estimate the number of photons emitted per second on an average by the source. (ii) Draw a plot showing the variation of photoelectric current versus the intensity of incident radiation on a given photosensitive surface.
- 6
Light of wavelength 2000 Å is incident on a metal surface of work function 4.2 eV in an experiment on photoelectric effect. (a) Find the maximum kinetic energy (in eV) of ejected photoelectrons. (b) If the intensity of light is doubled, find the change in stopping potential.
- 7
Plot a graph showing the variation of photoelectric current with intensity of light. The work function for the following metals is given: Na: 2.75 eV and Mo: 4.175 eV. Which of these will not give photoelectron emission for a radiation of wavelength 3300 Å from a laser beam? What happens if the source of laser beam is brought closer?
- 8
A beam of monochromatic radiation is incident on a photosensitive surface. Answer the following questions giving reasons: (a) Do the emitted photoelectrons have the same kinetic energy? (b) Does the kinetic energy of the emitted electrons depend on the intensity of incident radiation? (c) On what factors does the number of emitted photoelectrons depend?
- 9
Draw graphs showing the variation of photoelectric current with applied voltage for two incident radiations of equal frequency and different intensities. Mark the graph for the radiation of higher intensity.
- 10
Draw a graph showing variation of photocurrent with the anode potential of a photocell.
- 11
(a) Define the terms (i) threshold frequency and (ii) stopping potential in photoelectric effect. (b) Plot a graph of photocurrent versus anode potential for a radiation of frequency and intensities and ().
- 12
The variation of the stopping potential with the frequency () of the light incident on two different photosensitive surfaces and is shown in the figure (two parallel straight lines of the same slope, with the line crossing the frequency-axis at a LOWER frequency than the line, i.e. 's line lies to the left of 's). Identify the surface which has a greater value of the work function.
- 13
Estimate the frequency associated with a photon of energy 2 eV.
- 14
How would the stopping potential for a given photosensitive surface change if (i) the frequency of the incident radiation were increased, and (ii) the intensity of incident radiation were decreased? Justify your answer.
- 15
Two monochromatic radiations of frequencies and () and having the same intensity are, in turn, incident on a photosensitive surface to cause photoelectric emission. Explain, giving reason, in which case (i) more number of electrons will be emitted, and (ii) maximum kinetic energy of the emitted photoelectrons will be more.
- 16
The work function of a metal is 2.31 eV. Photoelectric emission occurs when light of frequency Hz is incident on the metal surface. Calculate: (i) the energy of the incident radiation, (ii) the maximum kinetic energy of the emitted electron, and (iii) the stopping potential of the surface.
- 17
Explain, giving reasons, for the following: (a) Photoelectric current in a photocell increases with the increase in the intensity of the incident radiation. (b) The stopping potential () varies linearly with the frequency () of the incident radiation for a given photosensitive surface, with the slope remaining the same for different surfaces.
- 18
The following graph shows the variation of photocurrent for a photosensitive metal: (Graph description: photocurrent on the vertical axis rises steeply from a negative value on the horizontal axis , then saturates, in the standard S-shaped photocurrent-vs-potential curve.) (a) Identify the variable on the horizontal axis. (b) What does the point on the horizontal axis represent? (c) Draw this graph for three different values of frequencies of incident radiation () for the same intensity. (d) Draw this graph for three different values of intensities of incident radiation () having the same frequency.
- 19
Describe briefly three experimentally observed features in the phenomenon of photoelectric effect.
Numericals
Every numerical set on this subtopic. Full working is at the end of the page.
- 20
Photons of energy 3.2 eV are incident on a photosensitive surface. If the stopping potential for the emitted electrons is 1.5 V, the work function for the surface is
- (a)
1.5 eV
- (b)
1.7 eV
- (c)
3.2 eV
- (d)
4.7 eV
- (a)
Answers & Solutions
Work the questions above first, then check yourself here. Each answer is set out the way it should be written in the paper.
If the frequency of the incident radiation increases, the kinetic energy of the ejected photoelectrons also increases (since ). Hence we would need to increase the (negative) retarding potential to stop them, i.e. the stopping potential INCREASES.
Curves 1 and 2 have the SAME stopping potential (i.e. the same threshold/x-intercept), and the stopping potential for a given frequency of light depends only on the material (work function), not on the intensity. So curves 1 and 2 are for the same material (differing only in intensity, hence differing saturation currents); curve 3, having a different stopping potential, is for the other material.
Yes. Photoelectric current (which is proportional to the number of photoelectrons emitted per second) is directly proportional to the intensity of the incident radiation, for a given frequency of light. This is because greater intensity means a greater number of photons striking the surface per second, and each photon (above the threshold frequency) can liberate one photoelectron, so more electrons are emitted per second.
By Einstein's photoelectric equation: and Subtracting: — using eV m directly: in eV eV So the new stopping potential is approximately V.
(i) The number of photons emitted per second is given by the ratio of the power emitted to the energy of each photon: (ii) Photoelectric current is directly proportional to the intensity of incident radiation (for a given frequency): the graph is a straight line through the origin, i.e. photoelectric current increases linearly with intensity of light.
(a) By Einstein's photoelectric equation: m, eV, J m. (b) The maximum kinetic energy (hence the stopping potential) of the emitted electrons does not depend upon the intensity of the incident light — it depends only on the frequency (wavelength) of light and the work function. So if the intensity is doubled at the same wavelength, there is NO change in the stopping potential; only the photoelectric current (number of photoelectrons) increases.
Graph: photoelectric current is directly proportional to intensity of light (for a fixed frequency) — a straight line passing through the origin. Energy of the incident photon: Since , molybdenum (Mo) will NOT show photoelectric emission, while sodium (Na, eV eV) will. Bringing the laser source nearer only increases the INTENSITY of light (more photons per second), not the energy of each photon. Since the photon energy is still below Mo's work function, no photoemission will occur from Mo even if the source is brought closer; for Na, bringing the source closer will only increase the photoelectric current (more photoelectrons per second), not their kinetic energy.
(a) No. Electrons in a metal do not all occupy the same energy level — some are more tightly bound than others (near the surface vs deeper inside), so they lose different amounts of energy escaping. Hence photoelectrons are emitted with a RANGE of kinetic energies, up to a maximum value . (b) No, the maximum kinetic energy of the emitted electrons depends only on the frequency of the incident radiation and the work function of the metal, NOT on the intensity of the radiation. (c) The number of photoelectrons emitted per second depends only on the INTENSITY of the incident radiation (for a given frequency above threshold) — more intensity means more photons striking the surface per second, hence more photoelectrons.
Both graphs are of the same shape — the photoelectric current rises from a common (negative) stopping potential on the -axis and saturates at a constant value for large positive — since both radiations have the same frequency (hence same stopping potential). The curve reaching a HIGHER saturation current level corresponds to the radiation of HIGHER intensity , while the curve with the lower saturation current corresponds to the lower intensity (); both curves cross the voltage axis at the same (negative) stopping potential .
The photocurrent rises steeply from a negative (retarding) anode potential (the stopping potential), where the current is zero, and then increases until it saturates at a constant SATURATION CURRENT for sufficiently large positive anode potential — the standard S-shaped photocurrent-vs-anode-potential curve.
(a)(i) Threshold frequency is the minimum frequency of incident radiation below which no photoelectric emission takes place, irrespective of the intensity of light. (ii) Stopping potential is the minimum (negative/retarding) potential applied to the anode w.r.t. the cathode at which the photoelectric current becomes zero. (b) The two graphs, for the same frequency but different intensities , both cross the voltage axis at the SAME stopping potential (since frequency is unchanged), but the curve for saturates at a HIGHER current level than the curve for — otherwise the two curves have identical shape, just scaled vertically.
Since 's line crosses the frequency axis at a HIGHER threshold frequency than 's, has the greater value of threshold frequency, and therefore has the greater value of WORK FUNCTION (since ).
Using : (i) As the incident frequency increases, the stopping potential also INCREASES (they are directly, linearly related through the above equation). (ii) There is NO effect on the stopping potential when the intensity of incident radiation changes (at a fixed frequency), since depends only on and , not on intensity — only the photoelectric current (saturation value) will change as the intensity changes.
Intensity (energy delivered per unit area per unit time), where is the number of photons incident per unit area per unit time. For the same intensity, (i) Since for the same intensity the number of photons (and hence photoelectrons) per unit area per unit time is LARGER for the smaller frequency, MORE electrons will be emitted in the case of (the smaller frequency). (ii) Maximum kinetic energy is more for the greater frequency, so (the larger frequency) gives photoelectrons of greater maximum kinetic energy.
(i) Energy of incident radiation: (ii) Maximum kinetic energy: (iii) Stopping potential:
(a) Photoelectric current is proportional to the number of photoelectrons emitted per second, which in turn is proportional to the number of photons incident per second, i.e. to the intensity of light (for a fixed frequency). Hence photocurrent increases with intensity. (b) By Einstein's photoelectric equation, . This is linear in with slope — since and are universal constants, this slope is the SAME for every photosensitive surface, regardless of the material (only the intercept , i.e. the work function, differs between materials).
(a) The variable on the horizontal axis is the COLLECTOR PLATE POTENTIAL. (b) The point on the horizontal axis represents the STOPPING POTENTIAL (the negative retarding potential at which the photocurrent falls to zero). (c) For three different frequencies (same intensity), the three curves saturate at the SAME photoelectric current (since intensity, hence the number of photons/electrons per second, is unchanged), but cross the potential axis at three DIFFERENT stopping potentials — with giving the stopping potentials in the order (most negative) further left, then , then (least negative) closer to the origin, since a higher frequency gives more energetic photoelectrons requiring a larger retarding potential to stop. (d) For three different intensities (same frequency), all three curves cross the potential axis at the SAME stopping potential (frequency unchanged), but saturate at three DIFFERENT current levels, with giving progressively higher saturation currents.
(i) Emission of photoelectrons starts as soon as light falls on the metal surface, i.e. there is no time lag between the incidence of light and the emission of photoelectrons. (ii) The emission of photoelectrons takes place only when the frequency of the incident radiation is above a certain critical value called the threshold frequency , which is characteristic of the metal emitting the electrons. Above the threshold frequency, the maximum kinetic energy with which photoelectrons are emitted is directly proportional to the frequency of the incident radiation. (iii) The maximum kinetic energy with which a photoelectron is emitted from a metallic surface is independent of the intensity of light and depends only upon its frequency.
By Einstein's photoelectric equation: Here energy of photon eV, stopping potential V, so eV of stopping potential eV. eV. Option (b).